-H2O” Systems Revisited: The Importance of Co-Precipitation

The mechanism of aqueous contaminant removal by elemental iron (Fe 0 ) materials (e.g., in Fe 0 -H2O systems) has been largely discussed in the “iron technology” literature. Two major removal mechanisms are usually discussed: (i) contaminant adsorption onto Fe 0 oxidation products, and (ii) contaminant reduction by Fe 0 , Fe II or H/H2. However, a closer inspection of the chemistry of the Fe 0 -H2O system reveals that co-precipitation could be the primary removal mechanism. The plausibility of contaminant co-precipitation with iron corrosion products as independent contaminant removal mechanism is discussed here. It shows that the current concept does not take into account that the corrosion product generation is a dynamic process in the course of which contaminants are entrapped in the matrix of iron hydroxides. It is recalled that contaminant co-precipitation with iron hydroxides/oxides is an unspecific removal mechanism. Contaminant co-precipitation as primary removal mechanism is compatible with subsequent reduction and explains why redoxinsensitive species are quantitatively removed. Adsorption and co-precipitation precede reduction and abiotic reduction, when it takes place, occurs independently by a direct (electrons from Fe 0 ) or an indirect (electrons from Fe II /H2) mechanism.